+1 on GuttormG's suggestion.
I rather assumed most reloaders measured their case capacity as a matter of course - my apologies for this.
My suggestion -
1. take a random sample of 10 cases of each brand (you could get away with fewer but you want a decent sample size). Cases must be fired in your rifle with the fired primer still in (to keep it watertight) - i.e. fire-formed cases, not resized.
2. Either number each case in each batch with a marker pen or draw a numbered grid on paper so you can keep track of each individual case.
3. Weigh each case (dry) on your powder scale and note down the mass.
4. Take some tap water and add a tiny drop of dishwashing liquid (or detergent of your choice) to break the meniscus when you fill the cartridge case to the brim. The soap isn't essential but then you need to pay careful attention to filling to the same level - a bulging meniscus complicates this.
5. Fill each case to the same level, flush with the case mouth. Weigh the full case on your scale and note down the mass for each. Don't stress about the case being upright - provided that all the water plus the case are being weighed, you're good. Make sure to dry the powder pan properly each time (your scale resetting to zero, or not, should also warn you if the pan isn't dry)
6. Now for each case subtract the value recorded in step 3 from the value in step 5. The difference is your H2O case capacity.
7. If you have a fascination with statistics, you can release your inner nerd and decide if there are outliers you wish to reject, play around with standard deviations and the like.
My own habit is to reject the highest and lowest and take the average case capacity of the remaining 8.
The average for each batch will answer your questions. If the two batches have the same ave H2O capacity, then carry on using the same load with confidence. The std deviation will also give you an idea of the consistency of the batch/brand - my experience has been that the more premium brands are much more consistent.
Not a big deal for a big bore but the benchrest guys foam at the mouth over this stuff.
I think for the purposes of this exercise, you can ignore the effects of temperature on water volume
Provided your water is NOT about to change into a solid or a gas, the deviation on volume at ambient temp is going to be insignificant.
You can run the different case capacities through an internal ballistics programme to see what impact it has on pressures/velocities.