I have some snap caps for a couple of my guns (not double rifles) and I just don't like them much. I don't think they're accurately sized (the .308 ones I have are definitely shorter than a live round) and they don't always want to cycle or chamber properly in some of my guns because of that (the 12-gauge ones I have are an exception). I'd rather use properly-sized dummy rounds with real casings (hot glue dab instead of a primer), painted bullets, and sand to simulate powder if I could. But that would be for cycling an action and practicing loading, not necessarily for making the hammer/pin fall on them. What
@Red Leg said about having some actual resistance for the hammer/pin is a good point (and on that subject, would a thick dab of hot glue provide sufficient resistance?).
But like I said, my problems aren't with a double. I think you'd be fine with snap caps as long as they were of good quality and ensured good contact/resistance with the pin/hammer.